Masterpow

MSDS#: KIP070102-PPC
Material Safety Data Sheet
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CRYSTAL NAILS MASTER POWDER CLEAR
Section 1 – Identification of the Substance/Preparation and of the Company/Undertakin
Material/Product Name: Master Powder Clear
MSDS Initial Approval Date: Chemical Name: N/A
MSDS Prepared by: BSQ Manufacturer/Distributor: Litrox Factory Investments LLC (443960-91)
Family: ACRYLIC POLYMER
US 8130 SW Portland, Oregon, Beaverton-Hillsdale Highway 97225. Product Use: NAIL POLYMER
Product #: 4021001
Section 2 - Composition/Information on Ingredients Section 2 - Composition/Information on Ingredients
Chemical Identity
CAS Numbers
INCI Name
Exposure Carcinogen Limits
Poly (ethyl methacrylate) 9003-42-3 Polyethylmethacrylate Dibenzoyl Peroxide Benzoyl peroxide N/E - None Established N/DA - No Data Available
N/A - Not N/R - Not Reviewed Applicable
Hazard Symbols: Xi
Risk Phrases: R36/37/38 Safety Phrases: S18, S22, S24/25, S38
This product is not considered hazardous by OSHA Hazard Communication Standard. Section 3 - Hazards Identification
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials. May cause allergic skin reaction. May cause eye irritation. Dust may cause irritation of the nose, throat, and lungs. This product may contain particulate, not otherwise classified (Nuisance Dust) Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry Eyes or skin (No absorption); inhalation of dust.
Higher concentration can irritate eyes. May cause eye irritation or damage. Repeated or prolonged exposure may cause allergic skin rashes. Higher concentration can irritate respiratory system. Possible temporary discomfort due to inhalation of dust concentration above the permissible exposure limit. Dust may cause irritation of the nose, throat, and lungs. Sub-Chronic EffectsFor Polymer: OSHA classifies this material as Particulates, Not Otherwise Classified. Eyes, skin and Respiratory tract may be irritated by gross overexposure to Particulates, Not Otherwise Classified, no matter how they are generated. Avoid inhalation of dust. Keep dust out of eyes to prevent possible irritation. For decomposition product: Methyl Methacrylate Monomer; Liquid or high vapor concentration can irritate eyes, respiratory system and cause skin rashes. Prolonged exposure can lead to headaches, nausea, staggering gait, confusion, drowsiness and unconsciousness. Repeated and prolonged over exposure may cause permanent brain and nervous system damage, allergic skin rashes, eye corrosion and permanent injury, as well as changes in liver and kidney function or damage. For Benzoyl Peroxide: repeated or prolonged contact may cause skin sensitization. NOTE: Refer to Section 11, Toxicological Information for Details Section 4 - First Aid Measures
First Aid for Eye Flush with water for 15 minutes, including under eyelids. Get medical help if discomfort persists. First Aid for Skin Wash with soap and water. Get medical help if discomfort persists. First Aid for Inhalation Remove to fresh air. Get medical help if discomfort persists. First Aid for Ingestion Rinse mouth out with water. Call doctor if amount was large. Revised Date: 12/21/2004 Replaces Date: 7/01/2002
MSDS#: KIP070102-PPC
Material Safety Data Sheet CRYSTAL NAILS MASTER POWDER CLEAR
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Section 5 - Fire Fighting Measures
Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
TAG Closed: 580ºF/304ºC N/A N/E Method:
Extinguishing Media:
Water, carbon dioxide, dry chemical. Avoid extinguishing methods that generate dust clouds. Water streams can disperse dust into air, producing a fire hazard and possible explosion hazard. Fire-fighters should wear self - contained breathing apparatus. Unusual Hazards: Po lymer dust is combustible, explosive limits of the polymer particles suspended in air are approximately those of coal dust.
Section 6 - Accidental Release Measures
Spill or Release Sweep up to avoid slipping hazard. Keep airborne particulates at a minimum when cleaning up spills. Procedures Section 7 - Handling and Storage
Observe precautions found on the label. Wash face and hands thoroughly with soap and water after handling and Handling Storage before eating, drinking or smoking.Avoid prolonged or repeated contact with skin. Avoid contamination. Use only with adequate ventilation. Store in cool, dry place away from heat, sparks, flame and direct sunlight. Close container after each use. Ground Explosion Hazard all metal conrainers when transferring. Use explosion-proof equipment Store away from combustibles and incompatible materials. Polymer dust is combustible, explosive limits of the polymer particles suspended in air are approximately those of coal dust. Section 8 - Exposure Controls / Personal Protective Equipment
Engineering Controls Use good local exhaust at processing equipment, including buffers, sanders, grinders and polishers . High temperature processing equipment should be well ventilated. Use explosion-proof equipment.Provide ventilation if necessary to control exposure levels below airborne exposure limits. Personal Protective Equipment
Dust collectors are recommended for handling powder in bulk.
Eye/ Face Protection Use safety glasses and have eye flushing equipment immediately available. Minimize contamination by following good industrial practice. Wearing nitrile, neoprene, pvc, latex ot other impermeable gloves is recommended. Respiratory Protection Avoid breathing dust and mist. Use dust mask. Section 9 - Physical and Chemical Properties
Appearance
Odor & Odor Threshold
Specific Gravity
Viscosity
% Volatile
Fine, white powder Faint odor in bulk. Boiling Point/
Evaporation
Ignition
Solubility
Freezing Point
Temperature
Partitioning Coefficien Pressure:
Flash Point(°F/°C) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
TAG Closed: 580ºF/304ºC N/A N/E Section 10 - Stability and Reactivity
Stability: Stable
Incompatibility (Materials to Avoid): Strong
Hazardous Decomposition Products: methacrylate monomers
Revised Date: 12/21/2004 Replaces Date: 7/01/2002
MSDS#: KIP070102-PPC
Material Safety Data Sheet CRYSTAL NAILS MASTER POWDER CLEAR
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Conditions to Avoid: Heating above 240 deg C , 464 deg F Hazardous Polymerization: will not occur
Section 11 - Toxicological Information
Acute Oral Toxicity
Acute Dermal Toxicity
Acute Inhalation Toxicity
Irritation - skin
Irritation - Eye
LD50 Oral (Rat) : 7990mg/kg LD50 Dermal (Rabbit): LC50 Inhalation (Rat) : >12,500 to 16,500 ppm for 0.5 hours Since this product contains a very low concentration of active components, the primary toxicological information is derived from the copolymers. Further hazardous properties cannot be excluded. The product should be handled with care when dealing with chemicals. Sensitization Mutagenicity Sub-chronic Toxicity
No information available No information available No information available Section 12 - Ecological Information
Ecotoxicological Information
Acute Toxicity
Acute Toxicity to
Acute Toxicity
Bioconcentratio n
Toxicity to
Sewage Bacteria
Flathead minnows and goldfish TLm24 : 420 ppm Bluegills TLm24 : 368 ppm Chemical Fate Information
Biodegradability Chemical
Oxygen Demand
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated. Do not allow to enter drinking water supplies, wastewater, or soil. Section 13 - Disposable Considerations
May be disposed of in a landfill or incinerated. Follow Federal, State and Local regulations for disposal. For EU Member States, please refer to any
relevant Community provisions relating to waste. In their absence, it is useful to remind the user that national or regional provisions may be in force.
Section 14 - Transport Information
DOT (49 CFR 172)
Proper Shipping Name:
Non-Regulated Material Identification Number: Marine Pollutant: Special Provisions: Emergency Response Guidebook (ERG) #:
IATA (DGR):
Proper Shipping Name:
Non-Regulated Material Class or Division: UN or ID Number: Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name:
Non-Regulated Material Class or Division: UN or ID Number: Special Provisions & Stowage/Segregation: Emergency Schedule (EmS)#:
Other Information:
Flash point > 100ºC
Section 15 - Regulatory Information
US Federal Regulations
Clean Air Act: HAP/ODS This product contains the following hazardous air pollutants (HAP's) or ozone dipleting substances (ODS's), as defined by the U. S. Clean Air Act: • NONE Clean Water Act: Priority Pollutant This product contains the following chemicals listed under the U.S. Clean Water Act Priority Pollutant List: • NONE FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and/ or Revised Date: 12/21/2004 Replaces Date: 7/01/2002

MSDS#: KIP070102-PPC
Material Safety Data Sheet CRYSTAL NAILS MASTER POWDER CLEAR
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other applications as an indirect food additive.
Occupational Safety and Health Act This product is not considered a hazardous chemical under the OSHA Hazard Communication Standard. This product contains no chemicals considered to be hazardous waste under RCRA ( 40 CFR 261).
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely hazardous substances.
SARA Title III: Section 302 (RQ) This product contains no chemicals regulated under Sec. 304 as extremely hazardous chemicals for emergency release notification ( "CERCLA " List). This product does SARA Title III: Section 311-312: not contain hazardous substances under the OSHA Hazard Communication Standard, and is not regulated under Section 311-312 (40 CFR 370).
SARA Title III: Section 313: This product contains the following chemicals outlined in SARA Title III: Section 313: • Benzoyl Peroxide CAS #94-36-0. This product contains chemicals listed on TSCA Section 8(b): Inventory: the TSCA inventory or otherwise complies with TSCA premanufacture notification requirements. None of the chemicals listed have a SNUR under TSCA.
TSCA Significant New Use Rule: Benzoyl Peroxide CAS #94-36-0 CA Right-to-Know Law: California No Significant Risk Rule: Benzoyl Peroxide CAS #94-36-0 MA Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0 NJ Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0 PA Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0 FL Right-to-Know Law: Benzoyl Peroxide CAS #94-36-0 MN Right-to-Know Law: CDSL: Canadian Inventory (on Polymethyl methacrylate CAS# 9011-14-7 is on the DSL List. WHMIS = n/da Canadian Transitional List) Benzoyl Peroxide CAS #94-36-0 is on the DSL list. WHMIS = C, D2B, B4 EINECS: European Inventory: HAZARD SYMBOLS: Xi: Irritant
RISK PHRASES: R36/37/38: Irritating to eyes, respiratory system and skin
SAFETY PHRASES: S18: Handle and open container with care, S22: do not
breath dust, S24/25: avoid contact with skin and eyes, S38: in case of
insufficient ventilation, wear suitable respiratory equipment. Section 16 - Other Information
* - Respiratory protection may be necessary depending on conditions of use. Refer to Section VIII of this MSDS for respiratory protection guidelines.
OSHA PEL for nuisance dust: 15 mg/m3 (total dust) 5 mg/m3 (respirable dust) ACGIH PEL for nuisance dust: 10 mg/m3 Revised Sections since Last Version: Section 2 % changed from <,> to range, headers changed, format update The information presented herein was obtained from sources considered to be reliable. However, this information is provided without any warranty, expressed or implied, regarding its correctness or suitability for consumers intended use and/or application. For this and other reasons, we assume no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared expressly for this product. Use the materials only as directed. If the product is used as a component of another product, the information contained within the MSDS may not be applicable. If one could have any concerns with or problems understanding this MSDS form, please direct all questions to INFOTRAC, Chemical Emergency Resources System at 1(800) 535-5053. Revised Date: 12/21/2004 Replaces Date: 7/01/2002

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